English | German dictionary Mäd•chen nt , - s, - girl (=Tochter auch) daughter dated. Freundin) girl(friend) (=Dienstmädchen) maid ein unberührtes Mädchen a virgin ein Mädchen für alles inf a dogsbody (Brit) , a gofer, (im Haushalt auch). Au- pair- Mädchen Au- pair- Mäd•chen nt , Aupairmädchen Au•pair•mäd•chen nt au pair (girl) als Au- pair- Mädchen arbeiten to work (as an) au pair Hw. G- Mädchen Hw. G- Mäd•chen nt (Admin, sl) girl listed by police or medical authorities as being promiscuous girl listed by police or medical authorities as being promiscuous. Linda.garofalo@ barbdavis50@ csantacruz96@ connect_to_me@ goffelec1@ tnlisaf@ dragonjly_01@ tjamestenn@ shortstud2005@ GAtwogees@ battles_ricky@ chazthorne@. Als ich im Sommer gefragt wurde, ob ich einen kreativen Beitrag für eine DIY-Beilage einer Zeitung machen möchte, habe ich natürlich nicht "nein" gesagt. Das Thema. Of all the trolls we've had on RMA, I think EisMadchen is one of the most underrated and least appreciated. She had a lot going for her. Junger Dokumentarfilm 2015; Eismädchen. Lisa, die ältere der Schwestern, versucht mit aller Kraft den Erwartungen, die sie an sich selbst stellt und die von. EisMadchen Featured By Owner Apr 28, 2013 Student Traditional Artist. ohhh. Reply. xXNeonWingsXx Featured By Owner Mar 3, 2013 Hobbyist Digital Artist. Reply. 12:16:16: Mark Goldberg: Remember the guy who got on a plane with a bomb built into his shoe.? From an email sent to me: Mark ----- Remember the. Lesen Sie Eismädchen Kriminalroman von Kate Rhodes mit Kobo. Eisiger Winter in London. Ein Serientäter tötet kleine Mädchen. Sein Muster: dasselbe wie das des. Paizo Games Kill Doctor Lucky; Save Doctor Lucky; Paizo. Http:// eismadchen. English (US) Español; Français (France) 中文(简体).
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Animal Care Center - Pima County. Our Commitment. Pima Animal Care Center's mission is to rescue pets in need, protect the community and save lives. Here are some of the ways we approach our mission: Providing shelter and second chances for abandoned pets, none of whom are turned away; Protecting public health and safety by enforcing laws and ordinances; Responding to and investigating complaints of animal abuse and cruelty; Working with more than five dozen rescue and animal welfare partners to find loving homes for homeless animals; Picking up stray dogs to increase safety for the animals and your neighborhood, while providing an opportunity for lost pets to be reunited with their owners; Promoting and supporting low- cost spay/neuter, vaccination and licensing services; Encouraging volunteers and donors to assist in our mission. Pima Animal Care Center is a Division of the Pima County Health Department and is organized into four major sections: Shelter, Enforcement, Licensing and Community Outreach. The Pima Animal Care Center is located in Tucson, with a substation in Ajo. See our Annual Statistics.
The Seattle Animal Shelter is responsible for enforcing the laws and codes involving animals within the City of Seattle. Nationwide Humane Animal Removal, Animal Control, Wildlife Removal and Wildlife Control professionals. Qualified Experts in Animal Removal.
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Black lung - Wikipedia. Black lung can mean several things.
Black Lung Benefits For WidowsPneumoconiosis. Pneumoconiosis is a general term given to any lung disease caused by dusts that are breathed in and then deposited deep in the lungs causing damage. · Black lung rates, especially among coal miners in Appalachia, are rising to levels not seen since the 1970s. This comes despite the enactment of coal dust. Melissa Grimm, secretary of the National Coalition of Black Lung and Respiratory Clinics, who is based in Martins Ferry, Ohio, said the uptick in the disease could be. Federal health researchers are visiting health clinics and medical schools in the Appalachian coalfields to recruit allies in the fight a resurgence of black lung. What is black lung disease? Black lung disease is a common name for any lung disease that develops from inhaling coal dust. This name comes from the fact that those. Black Lung ZoolanderYesterday, a proposed regulation that aims to eliminate black lung disease in coal miners was published in the Federal Register. The release of this proposed. SUBCHAPTER IV—BLACK LUNG BENEFITS Part A—General Provisions §901. Congressional findings and declaration of purpose; short title (a) Congress finds and declares. House Blend fue un piloto para una serie de televisión escrita por Anne Flett-Giordano y Cuck Ranberg y dirigida por John Whitesell. Fue hecha por Paramount Network. Buy House Blend Coffee KCup Packs from our Coffeehouse. Our House Blend Coffee K-Cup Packs are Sweet, Toasted-Nut, with a Subtle Hints of Chocolate. Home Firm Profile Our Projects Services Client Testimonials Our Crowd Contact Us. House-Blend.com © 2007 House Blend, Inc., all rights reserved Phone. House Blend. Postponed! Wed. Apr. 5, 7: 3. House Blend sings 3 songs as part of a Social Justice fund raiser with some great groups at the Guilford Community Church. Disfruta de la mejor taza de café en tu hogar o lugar de trabajo! Nuestro café House Blend le da un nuevo comienzo a tu día para que lo disfrutes en cualquier momento. House Blend - Acoustic Duo. 146 likes · 1 talking about this. We are an acoustic duo based in Montgomery/Bucks County. We cover a wide range of popular. House Blend, formed in 2. Vermont and New Hampshire, devoted to the collective exploration of the many styles of mostly a cappella songs from around the world and throughout musical history. A democratically- governed party of self- professed singing addicts, the "Blenders" look to the artistic direction of all of its members to guide the group, creating a harmonious brew that reflects their diverse musical backgrounds. Their first CD appeared in May 2. Loire Valley region of France in June with Chorale Cantoria. Their second CD, “Percolatin’,” came out in June 2. House Blend returned to France in 2. Upcoming gigs: 6/3/2. Strolling of the Heifers at the Vocal Entertainment Tent on the Brattleboro Retreat lawn, 1. Sample music. Listening to music clips on this site requires that you have the free Flash Player installed. Get it here. You can see our list of Past Performances. Brochure (pdf, 1. MB)Description of the House Blend - Cantoria Exchange (pdf, 2. KB)Contact: information@houseblend. Gill Truslow and Helen Anglos)Rehearsing by the Loire River, France, 2. House Blend Lighting And DesignDas Geisterhaus Isabel AllendeDas Geisterhaus [Isabel Allende -] on Amazon.com. *FREE* shipping on qualifying offers. Find album reviews, stream songs, credits and award information for Das Geisterhaus - Original Soundtrack on AllMusic - 1995. Thank you for helping! Your input will affect cover photo selection, along with input from other users. Das Geisterhaus Film OnlineDas Geisterhaus - Original Soundtrack | User Reviews.
Project Almanac - Movie Trailers. A high school student builds a time machine based on his late father's plans and convinces friends to join him in using it to their own advantage. Watch trailers. · Buy Project Almanac: Read 4417 Movies & TV Reviews - Amazon.com. Project Almanac (2. I'm going to take a stand right now and declare that Hollywood should simply stop making found footage movies. I don't hate the subgenre itself, and in fact a found footage approach can be rather interesting if given proper attention and care, but that is just not happening nearly enough. Project Almanac Full Movie Xmovies8Самая свежая и полная информация о фильме Континуум | Project Almanac: Истории на сайте KINOMANIA.RU. Too often Hollywood execs view found footage as a hook and slap it onto a story that does not need to be told in this limited style. There's no reason that a perfectly fine buddy cop movie like End of Watch needed a found footage angle, except that's probably how it was sold. Project Almanac Full Movie StreamIf you're going to do found footage you better have a god reason why your characters are recording every moment, and most do not. You better stick to the principle that the only viewpoint is from the camera, and most do not. And you better stick to the limitations of this viewpoint, meaning who is editing these things after the fact and adding popular music to make montages? Found footage is too often underdeveloped in approach, a lazy selling point because "the kids" today like documenting themselves doing everything. But really, can you name the last found footage hit? The Paranormal Activity franchise is on the downturn and the last critically lauded one was 2. Chronicle. Don't just stop making found footage movies because they're too often lackluster; stop making them because the public has grown indifferent. Now, with all that being said, the time travel flick Project Almanac proves once again to be a film that never needed to be found footage to work. As far as January releases go (usually a dumping ground for studio bombs) it's better than most, but the poorly titled sci- fi drama wastes its premise on the myopic doldrums of youth. David Raskin (Johnny Weston) wants to get into M. I. T. but his hard- working mother doesn't have the money to make this happen. He discovers an old video of his seventh birthday party and is shocked to see an image in the background that resembles him as a teenager. He and his friends, Quinn and Adam, investigate the video. They enter the basement lab that used to belong to David's father, until he died in a car accident shortly after that birthday recording. There they find plans for a time machine and the boys busily go to work assembling it, perfecting it, and charging it. Jessie (Sophia Black- D'Elia), a popular girl at school, stumbles into their first experiment and becomes part of the group. They have to keep this a secret and they must only travel back as a group. The freedom and possibilities are exhilarating, but soon enough David discovers a spiral of consequences that are difficult to correct without scrapping everything. From a structural standpoint, this movie gets pretty lopsided and completely misuses the possibilities it established even as it arbitrarily throws its own rules out the window. Project Almanac takes far too long to get the time machine working. The teens discover the manual but it takes almost the complete first act before they successfully travel in time. Why do we have to wait a full 3. It's not exactly like the audience demands a sense of scientific accuracy. Once the teens do travel through time, they set their sights very low: pass a test, get revenge on a bully, win the local lottery, and go to Lolapalooza. There is the limitation of only going back three weeks into the past, which eventually disappears, but could these kids not aim higher in their goals? When they do go to Lolapalooza, the movie drags and drags, and it's here where I started to theorize what became of this film (more on that below). Once we come back from the festival, David decides to jump back alone to stop himself from blowing his opening with his crush, Jessie. However, there are disastrous consequences stemming from this and he has to debate whether to undo his good fortune with Jessie. Want to know what those consequences include? · Rent Project Almanac (2015) and other Movies & TV Shows on Blu-ray & DVD. 1-month free trial! Fast, free delivery. No late fees. Project Almanac Movie. 402K likes. The official Facebook page of Project Almanac, in theaters this Friday. www.ProjectAlmanac.com. Project Almanac movie reviews & Metacritic score: A brilliant high school student and his friends uncover blueprints for a mysterious device with limitless p. Seventy- seven people dying in a plane crash. Our main character seriously agonizes about keeping his new girl or the lives of seventy- seven people. And what would he lose? It's not like he can't be suave around Jessie ANY OTHER TIME. All he has to do is say something and kiss her. The hesitation and struggle over this is comically absurd, but the struggle illuminates where Almanac could have gone. These teens could have used time travel to save lives, but I guess that's not as fun as seeing Imagine Dragons backstage and dancing. Another problem is that, from a time travel standpoint, this stuff doesn't really follow its own rules. The gang goes back at several points to repeat the same goal, but at no point do they run into different iterations of themselves. If they keep going back to fix things, and fail, and then go back again, that's a continuation of one ongoing timeline, not a do- over. Time doesn't reset. With every time travel story there's the nagging nature of paradoxes but Project Almanac just ignores them, hence the lack of doppelgangers. At one point, Quinn even seeks out his past self to pull a prank, which sounds really stupidly dangerous from a space- time continuum standpoint to me. The movie ignores paradoxes.. The entire third act is about the consequences of paradoxes, and now all of a sudden it matters. That doesn't work. The main third act conflict is David not wanting to lose his girlfriend. Project Almanac movie YIFY subtitles. Found footage movies are often pretty predictable and sketchy, but project almanac isn't. Континуум / Project Almanac (2014) смотреть онлайн hd бесплатно в хорошем качестве 720p. He keeps jumping back to fix this and fix that but it's all to save his girlfriend, which is pretty dumb, as I've pointed out already that Jessie could still decide on her own at any point in the future to be his gal. Then there's the conclusion, as we all know that we have to get back to that birthday party at some point. I consider myself a smart man but the end doesn't make any sense because (spoilers to follow) it invalidates the timeline that we witnessed. David makes it so the events will not happen and the machine will not be constructed. But why is there evidence? Why is there still a tape detailing this whole process? It should be wiped. Requisite found footage griping: why do they record every damn thing in this movie? The gang even breaks into their high school to steal hydrogen canisters from a locked science lab. Why would you record your crime spree? Why would you record people just driving in cars or walking up to school? Why would you record any of this? How do you clearly pick up audio from two people at a distance, mind you, at a freaking outdoor concert with lots of noise to cancel out any discernible dialogue? There are moments that I really liked, flashes that show how much fun or even clever Almanac could have been under other circumstances. One of these moments involves Quinn going back to save his grade. Originally he failed his chemistry presentation, so he thinks he'll easily pass thanks to the foreknowledge that time travel offers. He goes back, lists the first ten elements on the periodic table, and then his teacher asks him another question he wasn't prepared for. He goes back, prepared for the two, and then the teacher asks another he wasn't prepared for. Over the course of going back, he is actually forced to study to prepare for this presentation, and so even though he thought he would use time travel to be lazy, it forced him into doing what he should have done in the first place. When they go back to win the lottery, they accidentally write down one wrong number, so their first jackpot prize isn't the full amount. They bicker about going back, whose fault it was, and then the film cuts immediately to them holding the full amount in an oversized check. All the characters are devoid of excitement, because that excited moment of revelry already happened, and now this is just an exercise to get over. The photographer chides them to be more excited. That is a fun moment. The characters are rather likeable. There's another moment where Jessie realizes that David went back to fix a slipup so they would end up together. And she reacts exactly how she should, wounded and mistrusting. How can she trust what he says now? How can she not doubt every moment being carefully pre- programmed for a desired result? She was manipulated. This confrontation was missing from About Time where Rachel Mc. Adams would have learned that her charming husband traveled back in time dozens of times to perfect his courtship, thus manipulating her own sense of choice. Poor Rachel Mc. Adams never finds out, which seems like a completely blown dramatic development, and lives in cherished ignorance instead. At least Jessie gets to know the truth and behaves naturally. There are other little moments that are fun but they are distractions from what could have been. Allow me to do some serious speculation about Project Almanac's own past. This film was originally supposed to come out a year prior hence why every date is referenced as 2. MTV Films expressed some interest in the movie and it was shelved and likely retooled. Except with time travel films, retooling can be pretty monstrous with its carefully placed plot beats. Here's what I think happened. Originally, the third act was all about David going back to save his father from dying in that car crash. He likely does but there are dire consequences, and so he keeps going back to try and mitigate the negative repercussions while still keeping his father. Doesn't that sound like a much more emotionally involving storyline? He's got far more personal stakes in this scenario than simply losing his girlfriend who he can regain. He can't regain dear old dead dad. It seems preposterous to me from a screenwriting standpoint that they would introduce a deceased parent and not use time travel to save said parent. It's the ultimate setup. Instead, with MTV attached, we got to keep things lighter and more appealing to the carefree fun of youth, and so the gang goes to Lolapalooza instead where they can watch rock bands. I think MTV came in and jettisoned the third act and the direction of the script, imposing the festival, and reminding people how music is essential to being young and free and alive. Fat - Wikipedia. A fat, or triglyceride, molecule. Note the three fatty acid chains attached to the central glycerol portion of the molecule. Composition of fats from various foods, as percentage of their total fat. Dietary fats: Know which types to choose. When choosing fats, pick unsaturated fat over saturated fat. Here's how. By Mayo Clinic Staff. Http://photobucket.adnxs.com/pt?inv_code=empty&size=300x250&member=86&redir=//b.photobucket.com/pbkt/hserver/viewid=245184926/size=RECTANGLE/random=740263/area=empty. Fat is one of the three main macronutrients, along with carbohydrate and protein.[1] Fats, also known as triglycerides, are esters of three fatty acid chains and the alcoholglycerol. The terms "oil", "fat", and "lipid" are often confused. Oil" normally refers to a fat with short or unsaturated fatty acid chains that is liquid at room temperature, while "fat" may specifically refer to fats that are solids at room temperature. Father Of The Groom Speech ExamplesLipid" is the general term, though a lipid is not necessarily a triglyceride. Fats, like other lipids, are generally hydrophobic, and are soluble in organic solvents and insoluble in water. Fat is an important foodstuff for many forms of life, and fats serve both structural and metabolic functions. They are a necessary part of the diet of most heterotrophs (including humans).
Some fatty acids that are set free by the digestion of fats are called essential because they cannot be synthesized in the body from simpler constituents. There are two essential fatty acids (EFAs) in human nutrition: alpha- linolenic acid (an omega- 3 fatty acid) and linoleic acid (an omega- 6 fatty acid).[2][3] Other lipids needed by the body can be synthesized from these and other fats. Fats and other lipids are broken down in the body by enzymes called lipases produced in the pancreas. Fats and oils are categorized according to the number and bonding of the carbon atoms in the aliphatic chain. Fats that are saturated fats have no double bonds between the carbons in the chain. Unsaturated fats have one or more double bonded carbons in the chain. The nomenclature is based on the non- acid (non- carbonyl) end of the chain. Fatty Liver SymptomsThis end is called the omega end or the n- end. Thus alpha- linolenic acid is called an omega- 3 fatty acid because the 3rd carbon from that end is the first double bonded carbon in the chain counting from that end. Some oils and fats have multiple double bonds and are therefore called polyunsaturated fats. Unsaturated fats can be further divided into cis fats, which are the most common in nature, and trans fats, which are rare in nature. Unsaturated fats can be altered by reaction with hydrogen effected by a catalyst. This action, called hydrogenation, tends to break all the double bonds and makes a fully saturated fat. To make vegetable shortening, then, liquid cis- unsaturated fats such as vegetable oils are hydrogenated to produce saturated fats, which have more desirable physical properties e. Certain foods have a very high thermogenic effect, so you literally burn calories as you chew. C), and store well, whereas polyunsaturated oils go rancid when they react with oxygen in the air. However, trans fats are generated during hydrogenation as contaminants created by an unwanted side reaction on the catalyst during partial hydrogenation. Saturated fats can stack themselves in a closely packed arrangement, so they can solidify easily and are typically solid at room temperature. For example, animal fats tallow and lard are high in saturated fatty acid content and are solids. Olive and linseed oils on the other hand are unsaturated and liquid. Fats serve both as energy sources for the body, and as stores for energy in excess of what the body needs immediately. Each gram of fat when burned or metabolized releases about 9 food calories (3. J = 8. 8 kcal).[3] Fats are broken down in the healthy body to release their constituents, glycerol and fatty acids. Glycerol itself can be converted to glucose by the liver and so become a source of energy. Chemical structure. Example of a natural triglyceride with three different fatty acids. One fatty acid is saturated (blue highlighted), another contains one double bond within the carbon chain (green highlighted). The third fatty acid (a polyunsaturated fatty acid, highlighted in red) contains three double bonds within the carbon chain. All carbon- carbon double bonds shown are cis isomers. There are many different kinds of fats, but each is a variation on the same chemical structure. All fats are derivatives of fatty acids and glycerol. Most fats are glycerides, particularly triglycerides (triesters of glycerol). One chain of fatty acid is bonded to each of the three - OH groups of the glycerol by the reaction of the carboxyl end of the fatty acid (- COOH) with the alcohol; I. Water is eliminated and the carbons are linked by an - O- bond through dehydration synthesis. This process is called esterification and fats are therefore esters. As a simple visual illustration, if the kinks and angles of these chains were straightened out, the molecule would have the shape of a capital letter E. The fatty acids would each be a horizontal line; the glycerol "backbone" would be the vertical line that joins the horizontal lines. Fats therefore have "ester" bonds. The properties of any specific fat molecule depend on the particular fatty acids that constitute it. Fatty acids form a family of compounds that are composed of increasing numbers of carbon atoms linked into a zig- zag chain (hydrogen atoms to the side). The more carbon atoms there are in any fatty acid, the longer its chain will be. Long chains are more susceptible to intermolecular forces of attraction (in this case, van der Waals forces), and so the longer ones melt at a higher temperature (melting point). Fatty acid chains may also differ by length, often categorized as short to very long. Short- chain fatty acids (SCFA) are fatty acids with aliphatic tails of fewer than six carbons (i. Medium- chain fatty acids (MCFA) are fatty acids with aliphatic tails of 6–1. Long- chain fatty acids (LCFA) are fatty acids with aliphatic tails 1. Very long chain fatty acids (VLCFA) are fatty acids with aliphatic tails longer than 2. Any of these aliphatic fatty acid chains may be glycerated and the resultant fats may have tails of different lengths from very short triformin to very long, e. Long chain fats are exemplified by tallow (lard) whose chains are 1. Most fats found in food, whether vegetable or animal, are made up of medium to long- chain fatty acids, usually of equal or nearly equal length. Many cell types can use either glucose or fatty acids for this energy. In particular, heart and skeletal muscle prefer fatty acids. Despite long- standing assertions to the contrary, fatty acids can also be used as a source of fuel for brain cells.[citation needed]Importance for living organisms. Fats are also sources of essential fatty acids, an important dietary requirement. They provide energy as noted above. Vitamins. A, D, E, and K are fat- soluble, meaning they can only be digested, absorbed, and transported in conjunction with fats. Fats play a vital role in maintaining healthy skin and hair, insulating body organs against shock, maintaining body temperature, and promoting healthy cell function. Fat also serves as a useful buffer against a host of diseases. When a particular substance, whether chemical or biotic, reaches unsafe levels in the bloodstream, the body can effectively dilute—or at least maintain equilibrium of—the offending substances by storing it in new fat tissue. This helps to protect vital organs, until such time as the offending substances can be metabolized or removed from the body by such means as excretion, urination, accidental or intentional bloodletting, sebum excretion, and hair growth. Adipose tissue. The obesemouse on the left has large stores of adipose tissue. For comparison, a mouse with a normal amount of adipose tissue is shown on the right. In animals, adipose, or fatty tissue is the body's means of storing metabolic energy over extended periods of time. Adipocytes (fat cells) store fat derived from the diet and from liver metabolism. Under energy stress these cells may degrade their stored fat to supply fatty acids and also glycerol to the circulation. These metabolic activities are regulated by several hormones (e. The location of the tissue determines its metabolic profile: visceral fat is located within the abdominal wall (i. Visceral fat was recently discovered to be a significant producer of signaling chemicals (i. One of these is resistin which has been linked to obesity, insulin resistance, and Type 2 diabetes. This latter result is currently controversial, and there have been reputable studies supporting all sides on the issue. Fatty acids and human health. Dietary consumption of fatty acids has effects on human health. Studies have found that replacing saturated fats with cis unsaturated fats in the diet reduces risk of cardiovascular disease. For example, a 2. Cochrane Library concluded: "Lifestyle advice to all those at risk of cardiovascular disease and to lower risk population groups should continue to include permanent reduction of dietary saturated fat and partial replacement by unsaturated fats."[4]Numerous studies have also found that consumption of trans fats increases risk of cardiovascular disease.[2][3] The Harvard School of Public Health advises that replacing trans fats and saturated fats with cis monounsaturated and polyunsaturated fats is beneficial for health.[5]See also. References^"Macronutrients: the Importance of Carbohydrate, Protein, and Fat". Mc. Kinley Health Center. University of Illinois at Urbana- Champaign. Retrieved 2. 0 September 2. Mozaffarian, Dariush; Katan, Martijn B.; Ascherio, Alberto; Stampfer, Meir J.; Willett, Walter C. Trans Fatty Acids and Cardiovascular Disease". New England Journal of Medicine. NEJMra. 05. 40. 35. ISSN 0. 02. 8- 4. PMID 1. 66. 11. 95. United Kingdom The Food Labelling Regulations 1. Schedule 7: Nutrition labelling^Hooper et al., "Reduction in saturated fat intake for cardiovascular disease",Cochrane Database Syst Rev. Jun 1. 0; (6): CD0. Fats and Cholesterol", Harvard School of Public Health. Retrieved 0. 2- 1. Fatty acid - Wikipedia. Not to be confused with fat. In chemistry, particularly in biochemistry, a fatty acid is a carboxylic acid with a long aliphatic chain, which is either saturated or unsaturated. Most naturally occurring fatty acids have an unbranched chain of an even number of carbon atoms, from 4 to 2. Fatty acids are usually derived from triglycerides or phospholipids. Fatty acids are important dietary sources of fuel for animals because, when metabolized, they yield large quantities of ATP. Many cell types can use either glucose or fatty acids for this purpose. Long- chain fatty acids cannot cross the blood–brain barrier (BBB) and so cannot be used as fuel by the cells of the central nervous system; [citation needed] however, free short- chain fatty acids and medium- chain fatty acids can cross the BBB,[2][3] in addition to glucose and ketone bodies. Types of fatty acids[edit]. Three- dimensional representations of several fatty acids. Fatty acids that have carbon–carbon double bonds are known as unsaturated. Fatty acids without double bonds are known as saturated. They differ in length as well. Length of free fatty acid chains[edit]Fatty acid chains differ by length, often categorized as short to very long. Unsaturated fatty acids[edit]Unsaturated fatty acids have one or more double bonds between carbon atoms. Pairs of carbon atoms connected by double bonds can be saturated by adding hydrogen atoms to them, converting the double bonds to single bonds. Therefore, the double bonds are called unsaturated.)The two carbon atoms in the chain that are bound next to either side of the double bond can occur in a cis or trans configuration. A cis configuration means that the two hydrogen atoms adjacent to the double bond stick out on the same side of the chain. The rigidity of the double bond freezes its conformation and, in the case of the cis isomer, causes the chain to bend and restricts the conformational freedom of the fatty acid. The more double bonds the chain has in the cis configuration, the less flexibility it has. When a chain has many cis bonds, it becomes quite curved in its most accessible conformations. For example, oleic acid, with one double bond, has a "kink" in it, whereas linoleic acid, with two double bonds, has a more pronounced bend. Linolenic acid, with three double bonds, favors a hooked shape. The effect of this is that, in restricted environments, such as when fatty acids are part of a phospholipid in a lipid bilayer, or triglycerides in lipid droplets, cis bonds limit the ability of fatty acids to be closely packed, and therefore can affect the melting temperature of the membrane or of the fat. A trans configuration, by contrast, means that the adjacent two hydrogen atoms lie on opposite sides of the chain. As a result, they do not cause the chain to bend much, and their shape is similar to straight saturated fatty acids. In most naturally occurring unsaturated fatty acids, each double bond has three n carbon atoms after it, for some n, and all are cis bonds. Most fatty acids in the trans configuration (trans fats) are not found in nature and are the result of human processing (e. The differences in geometry between the various types of unsaturated fatty acids, as well as between saturated and unsaturated fatty acids, play an important role in biological processes, and in the construction of biological structures (such as cell membranes). Examples of Unsaturated Fatty Acids. Common name. Chemical structureΔx. C: Dn−x. Myristoleic acid. CH3(CH2)3. CH=CH(CH2)7. COOHcis- Δ9. 14: 1n−5. Palmitoleic acid. CH3(CH2)5. CH=CH(CH2)7. COOHcis- Δ9. 16: 1n−7. Sapienic acid. CH3(CH2)8. CH=CH(CH2)4. COOHcis- Δ6. Oleic acid. CH3(CH2)7. CH=CH(CH2)7. COOHcis- Δ9. Elaidic acid. CH3(CH2)7. CH=CH(CH2)7. COOHtrans- Δ9. Vaccenic acid. CH3(CH2)5. CH=CH(CH2)9. COOHtrans- Δ1. Linoleic acid. CH3(CH2)4. CH=CHCH2. CH=CH(CH2)7. COOHcis,cis- Δ9,Δ1. Linoelaidic acid. CH3(CH2)4. CH=CHCH2. CH=CH(CH2)7. COOHtrans,trans- Δ9,Δ1. Linolenic acid. CH3. CH2. CH=CHCH2. CH=CHCH2. CH=CH(CH2)7. COOHcis,cis,cis- Δ9,Δ1. Arachidonic acid. CH3(CH2)4. CH=CHCH2. CH=CHCH2. CH=CHCH2. CH=CH(CH2)3. COOHNISTcis,cis,cis,cis- Δ5Δ8,Δ1. Eicosapentaenoic acid. CH3. CH2. CH=CHCH2. CH=CHCH2. CH=CHCH2. CH=CHCH2. CH=CH(CH2)3. COOHcis,cis,cis,cis,cis- Δ5,Δ8,Δ1. Erucic acid. CH3(CH2)7. CH=CH(CH2)1. 1COOHcis- Δ1. Docosahexaenoic acid. CH3. CH2. CH=CHCH2. CH=CHCH2. CH=CHCH2. CH=CHCH2. CH=CHCH2. CH=CH(CH2)2. COOHcis,cis,cis,cis,cis,cis- Δ4,Δ7,Δ1. Essential fatty acids[edit]Fatty acids that are required by the human body but cannot be made in sufficient quantity from other substrates, and therefore must be obtained from food, are called essential fatty acids. There are two series of essential fatty acids: one has a double bond three carbon atoms away from the methyl end; the other has a double bond six carbon atoms away from the methyl end. Humans lack the ability to introduce double bonds in fatty acids beyond carbons 9 and 1. Two essential fatty acids are linoleic acid (LA) and alpha- linolenic acid (ALA). They are widely distributed in plant oils. The human body has a limited ability to convert ALA into the longer- chain omega- 3 fatty acids — eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA), which can also be obtained from fish. Saturated fatty acids[edit]Saturated fatty acids have no double bonds. Thus, saturated fatty acids are saturated with hydrogen (since double bonds reduce the number of hydrogens on each carbon). Because saturated fatty acids have only single bonds, each carbon atom within the chain has 2 hydrogen atoms (except for the omega carbon at the end that has 3 hydrogens). Arachidic acid, a saturated fatty acid. Nomenclature[edit]Numbering of the carbon atoms in a fatty acid[edit]. Numbering of carbon atoms. The position of the carbon atoms in a fatty acid can be indicated from the COOH- (or carboxy) end, or from the –CH3 (or methyl) end. If indicated from the - COOH end, then the C- 1, C- 2, C- 3, ….(etc.) notation is used (blue numerals in the diagram on the right, where C- 1 is the –COOH carbon). If the position is counted from the other, –CH3, end then the position is indicated by the ω- n notation (numerals in red, where ω- 1 refers to the methyl carbon). The positions of the double bonds in a fatty acid chain can, therefore, be indicated in two ways, using the C- n or the ω- n notation. Thus, in an 1. 8 carbon fatty acid, a double bond between C- 1. C- 1. 3 (or ω- 6) is reported either as Δ1. COOH end (indicating only the “beginning” of the double bond), or as ω- 6 (or omega- 6) if counting from the –CH3 end. The “Δ” is the Greek letter “delta”, which translates into “D” ( for Double bond) in the Roman alphabet. Omega (ω) is the last letter in the Greek alphabet, and is therefore used to indicate the “last” carbon atom in the fatty acid chain. Since the ω- n notation is used almost exclusively to indicate the positions of the double bonds close to the –CH3 end in essential fatty acids, there is no necessity for an equivalent “Δ”- like notation - the use of the “ω- n” notation always refers to the position of a double bond. Fatty acids with an odd number of carbon atoms are called odd- chain fatty acids, whereas the rest are even- chain fatty acids. The difference is relevant to gluconeogenesis. Naming of fatty acids[edit]The following table describes the most common systems of naming fatty acids. System. Example. Explanation. Trivial nomenclature. Palmitoleic acid. Trivial names (or common names) are non- systematic historical names, which are the most frequent naming system used in literature. Most common fatty acids have trivial names in addition to their systematic names (see below). These names frequently do not follow any pattern, but they are concise and often unambiguous. Systematic nomenclature(9. Z)- octadecenoic acid. Systematic names (or IUPAC names) derive from the standard IUPAC Rules for the Nomenclature of Organic Chemistry, published in 1. Counting begins from the carboxylic acid end. Double bonds are labelled with cis- /trans- notation or E- /Z- notation, where appropriate. This notation is generally more verbose than common nomenclature, but has the advantage of being more technically clear and descriptive.Δx nomenclaturecis,cis- Δ9,Δ1. In Δx (or delta- x) nomenclature, each double bond is indicated by Δx, where the double bond is located on the xth carbon–carbon bond, counting from the carboxylic acid end. Each double bond is preceded by a cis- or trans- prefix, indicating the configuration of the molecule around the bond. For example, linoleic acid is designated "cis- Δ9, cis- Δ1. This nomenclature has the advantage of being less verbose than systematic nomenclature, but is no more technically clear or descriptive. A double bond is located on the xth carbon–carbon bond, counting from the terminal methyl carbon (designated as n or ω) toward the carbonyl carbon. For example, α- Linolenic acid is classified as a n−3 or omega- 3 fatty acid, and so it is likely to share a biosynthetic pathway with other compounds of this type. The ω−x, omega- x, or "omega" notation is common in popular nutritional literature, but IUPAC has deprecated it in favor of n−x notation in technical documents.[8] The most commonly researched fatty acid biosynthetic pathways are n−3 and n−6. Lipid numbers. 18: 3. Lipid numbers take the form C: D, where C is the number of carbon atoms in the fatty acid and D is the number of double bonds in the fatty acid (if more than one, the double bonds are assumed to be interrupted by CH2 units, i. This notation can be ambiguous, as some different fatty acids can have the same numbers. Consequently, when ambiguity exists this notation is usually paired with either a Δx or n−x term.[8] Esterified, free, unsaturated, conjugated[edit]When fatty acids circulating in the plasma (plasma fatty acids) are not in their glycerol ester form (glycerides), they are known as non- esterified fatty acids (NEFAs) or free fatty acids (FFAs). Starting out : the making of Jerzy Skolimowski's Deep End - Film 2. Eine Dokumentation über Jerzy Skolimowskis Klassiker „Deep End” von 1. Interviews der Beteiligten, u. Regisseur und Drehbuchautor Skolimowski, Chefkameramann Charly Steinberger und zwei Stars des Film – Jane Asher und John Moulder- Brown. Verleiher- Weitere Details. Produktionsjahr. 20. Filmtyp. Spielfilm. Wissenswertes- Budget- Sprachen- Produktions- Format- Farb- Format. Farbe. Tonformat- Seitenverhältnis- . SeriesHD Starting Out: The Making of Jerzy Skolimowski's Deep End ONLINE A fascinating and absorbing documentary about the making of Jerzy Skolimowski's. Highlight. Browse the fourth issue of BFI Filmmakers magazine; I want to See projects backed by the BFI. Get help as a new filmmaker. Find out what BFI Player. Starting Out: The Making of Jerzy Skolimowski’s Deep End stream swesub online subtitrat. Streama film Starting Out: The Making of Jerzy Skolimowski’s Deep End. Starting Out: The Making of Jerzy Skolimowski's Deep End (2011) A fascinating and absorbing documentary about the making of Jerzy Skolimowski's cult favourite, DEEP. Get more information about Starting Out: The Making of Jerzy Skolimowski's Deep End on TMDb. Jerzy Kosiński Written WorksStarting Out: The Making of Jerzy Skolimowski's Deep End (2. Value. A fascinating and absorbing documentary about the making of Jerzy Skolimowski's cult favourite, DEEP END, which was shot in 1. US- German co- production on location in London and Munich. The film's two stars, Jane Asher and John Moulder- Brown, 2. Skolimowski chronicles the production history from the writing of the script to the film's acclaimed first showing at the Venice Film Festival. Director of photography Charly Steinberger revisits some of the original locations and explains how he managed to shoot almost the entire film with a hand- held camera. Jerzy Kosinski QuotesAlso on board are production designer Anthony Pratt, editor Barrie Vince, and actor Christopher Sandford, each of whom contributes his own version of how DEEP END was part of the sixties' "swinging London"; and at the same time tilted it on its head. Pozostałe informacje o filmie Starting Out: The Making of Jerzy Skolimowski's Deep End. Stream Starting Out: The Making of Jerzy Skolimowski's Deep End online free. A fascinating and absorbing documentary about the making of Jerzy Skolimowski's cul. Starting Out: The Making of Jerzy Skolimowski's Deep End Trailer (2011) 02 January 2011. A fascinating and absorbing documentary about the making of Jerzy Skolimowski. Do you like Starting Out: The Making of Jerzy Skolimowski's Deep End? Comment in Facebook. Rejected Gremlins 3 Pitch Answers Big Question About Mogwai Rules. Whether you like it or not, Warner Bros. Gremlins movie. Once rumored to be a remake of the original 1. Gremlins is a 1984 American comedy horror film directed by Joe Dante and released by Warner Bros. The film is about a young man who receives a strange creature called. November 28, 2015 ‘Gremlins 3’ Is Happening, But It Won’t Be A Remake And Zach Galligan Wants In — What About Gizmo? New Gremlins Movie 2016'/videos/search?format=&mkt=&q=Gremlins+3&ru=%2fsearch%3fformat%3d%26mkt%3d%26q%3dGremlins%2b3&view=detail&mmscn=vwrc&mid=B6CF690FE87B069CD7F7B6CF690FE87B069CD7F7&FORM=WVFSTD' h='ID=SERP,5801.1'>Watch video · Zach Galligan has confirmed there are plans to make a third Gremlins movie and it will reference the events that took place in the 1984 original film. Find great deals on eBay for gremlins 3 and gremlins 3 movie. Shop with confidence. · The Gremlins have returned! No, Gremlins 3 hasn’t been given the greenlight. Although, I’m sure some Hollywood executive is sitting at his desk reading. Gremlins 3 is in works, and if producer Chris Columbus has his way it’s going to happen eventually. During a recent interview with Bleeding Cool, Gremlins star Zack. We don’t know much about what the long-rumored Gremlins 3 will be, other than the fact that we’re fairly confident it will eventually exist. Jurassic World. While we don’t know any specifics of the story, it has been said that the movie will keep the original film’s mythology intact while retelling the same story 3. Carl Ellsworth (Goosebumps) was the last writer reported to be hired on the Gremlins reboot back in April of last year, but some details on one of the rejected ideas for the project have just come to light thanks to Freddy vs. Jason writers Damian Shannon and Mark Swift posting a couple of pages from their pitch. Even though this story won’t make it to the big screen, it’s cool to see how this rejected Gremlins 3 pitch answers a big question about one of the three Mogwai rules. If you’ve seen Gremlins, then you know the little furry creatures known as Mogwai must be cared for with consideration for these three rules: Don’t get them wet. Don’t expose them to bright light. Don’t feed them after midnight. However, fans have always wondered how the concept of feeding Mogwai after midnight works when dealing with changing time zones. For example, if a Mogwai is on a plane, crossing time zones, does it have to be after midnight in that time zone or is there a specific time zone that applies to the Mogwai? An answer is found in the aforementioned two pages from the rejected reboot pitch that were just posted to Twitter by Shannon and Swift (via Movie. Web). Following a gunfight in Tibet after the theft of a familiar wooden box, a tattooed man makes it onto a plane after bribing customs officials to let him on with his acquisition. Inside the box is the familiar furry friend Gizmo and another Mogwai which starts making noise because it’s hungry. The man considers feeding the hungry Mogwai part of his Power Bar, but thinks better of the situation after asking the stewardess is unable to determine whether it’s truly after midnight due to flying over timezones. So it would seem that the rules of the Mogwai adhere to the manmade creation of time zones, which doesn’t exactly make sense. I’ve always thought a universal midnight would work better for the rules, but that’s not how it works in the original film, so this explanation serves the mythology better. What follows after this is an opening sequence reminiscent of the iconic Twilight Zone episode “Terror at 2. Feet” which was remade for Twilight Zone: The Movie by director George Miller. When a kid opens a bag of peanuts that spills all over the plane’s cabin, the hungry Mogwai gets his hand on a single peanut, prompting that signature “Uh- oh” from Gizmo. The fed Mogwai escapes after turning into his slimy monster form and causes the plane to have a crash landing in a suburb. It’s there that a young boy stumbles upon the box with Gizmo still inside and keeps the pet for himself. The other two Mogwai rules are never mentioned or discussed, though surely their consequences are discovered, presumably unleashing the little monsters on yet another unsuspecting town. If you want to read the full two pages from this rejects pitch, check out the full Twitter post right here. As for the story that will end up on the big screen, Chris Columbus has said that getting the new Gremlins movie off the ground is a slow process, so we have no timeframe as to when it might come together. Cool Posts From Around the Web. Gremlins 3 2018'/videos/search?format=&mkt=&q=Gremlins+3&ru=%2fsearch%3fformat%3d%26mkt%3d%26q%3dGremlins%2b3&view=detail&mmscn=vwrc&mid=7C53D10F204672BB99C67C53D10F204672BB99C6&FORM=WVFSTD' h='ID=SERP,5797.1'>Watch video · Zach Galligan says that the success of a "Jurassic World," a movie that is set decades after the original, has had an influence on the making of "Gremlins 3.". Billy's son, Brad goes on vacation with Gizmo to Oahu and later learn about little demon or "Hawaiian Gremlin" that are extinct for a thousand years ago. An unofficial Gremlins 3 poster. Another Unofficial Gremlins 3 poster. Gremlins 3 is the rumored sequel to Gremlins 2: The New Batch which was released in 1990. Gremlins 3 'definitely' in the works according to film's star Zach Galligan. Gremlins 3 is 'definitely' in the works. Zach Galligan, who played Billy Peltzer in the first two movies in the franchise, has confirmed Warner Bros. Chris Columbus is 'aggressively working' on the forthcoming film.'Warner Bros wants it': Gremlins 3 is 'definitely' in the works says the film's former star, Zach Galligan, 5. He is pictured in LA on June 2. Pals: Galligan is pictured in a movie still with his furry co- star. He said: 'He has been aggressively working on a Gremlins 3 that takes place in present day. He tantalisingly says there will be some new characters and some old characters - I guess in the style of a Force Awakens type sequel - One thing we know for sure is they have a writer on board.'Warner Bros definitely wants it, Chris Columbus wants to do it because he'd like to undo the Gremlins ' thing as he wasn't thrilled with it and Spielberg wants to do it I imagine - because he's Spielberg - and why wouldn't he want to do it.'Once he's found the right script he can attach his name and make a ton of money. Not that there's anything wrong with that.'Who will get it? The actor says that both Chris Columbus, 5. Steven Spielberg, 6. Galligan, 5. 2, insists Columbus 'regrets' not working on Gremlins 2 but he has since 'wrestled control back' on the third movie in the franchise. He added to Bleeding Cool: 'I think you can tell what's happening with Gremlins 3 the same way you could tell with Gremlins 2.''It's the same people and they tend to work the same way. There is a huge time gap but it's Warner Bros, Spielberg and Chris Columbus.''Now, Chris Columbus didn't have anything to do with Gremlins 2 - because by his own admission he didn't see a franchise.'From the past: The original comedy horror movie also starred Phoebe Cates'He kind of regrets it I believe, but he was one and done. I don't think he cared for Gremlins 2 and the direction some of the characters went in, so he's kind of wrested control back.''Everything I'm quoting is stuff he's publicly said, "There will never be a remake, there will never be a reboot there will only be a sequel."'The original comedy horror movie - which also starred Phoebe Cates and Corey Feldman - was released in 1. Galligan's young character receive a strange created called a mogwai which spawns evil monsters. Gremlins 2 dropped in 1. |
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